Bob it will be difficult to purify any alkoxide solution containing 5% water to get pure sodium ethoxide. Sciencemadness discussion board sodium ethoxide with. Sigmaaldrich offers sigmaaldrich71210, sodium ethoxide for your research needs. The addition rate is adjusted so that the reaction does not become. Ethoxide definition and meaning collins english dictionary. To the clear solution is added slowly 685 gm of nbutyl bromide. Reaction of 2bromopropane with ethoxide gives primarily elimination, but similar reaction with the malonate anion gives the substitution product 27. The reaction is so exothermic that ignition is possible. Find msds or sds, a coa, data sheets and more information. Application of skinprotective barrier cream is recommended. Ac168590000, ac168590010, ac168590025, ac168590050, ac168592500, ac168595000 ac168595000 synonyms. Sigmaaldrich 3050 spruce street saint louis mo 63103 usa telephone.
The number of electrons in each of sodium s shells is 2, 8, 1 and its electron configuration is ne 3s 1. The reaction commences almost immediately and considerable heat is generated. Safety data sheet of 6 infosafe no 1ch6f issue date. Sds of sodium ethoxide, safety data sheets, cas 141526. Sodium ethoxide c2h5ona or c2h5nao cid 2723922 structure, chemical names, physical and chemical properties, classification, patents, literature. Sodium ethoxide, 95% ch3ch2ona sodium ethylate sigma. Sodium ethoxide is the organic compound which dissolves in polar solvents such as ethanol.
This in a way helps to create sodium ethoxide in a liquid form. If the starting material is an ethyl ester, transesterification is irrelevant since the product is identical to the starting material. Identification product name sodium ethoxide, 21% ww in ethanol cat no. Sodium ethoxide is an alkoxide salt mainly used as a strong base in organic reactions such as deprotonation, dehydration and dehalogenation. Handling and storage avoid generation or accumulation of dusts.
Firstaid measures general advice show this safety data sheet to the doctor in attendance. Msds contains all of the information required by those regulations. The resulting solution, which is colorless, is often used as a source of sodium methoxide, but the pure material can be isolated by evaporation followed by heating to remove residual methanol. Safety data sheet creation date 09sep2009 revision date 22feb2018 revision number 1 1. This sodium ethoxide chemical, when mixed with water, that reacts to produce ethyl alcohol and ethanol.
L83 synonyms no information available recommended use laboratory chemicals. Sodium ethoxide 141 526 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. Well, this sodium ethoxide chemical is very dangerous for human health when it comes to contact with your skin as well as eyes. Uses advised against not for food, drug, pesticide or biocidal product use details of the supplier of the safety data sheet. Suppply high purity sodium ethoxide cas 141526 powder and solution sodium ethoxide ethanol solution 1. Additional technical, research and safety msds information is available as is a reference calculator for converting relevant units of measurement. Sodium ethoxide 141526 buy and find out price and availability, msds, properties of tcis high quality specialty chemicals. In mixed claisen condensations, a nonnucleophilic base such as lithium diisopropylamide, or lda, may be used, since only one compound is. Ethoxide and the malonate anionare about equal in basicity, 56 but ethoxide is a much harderbase. S sodium methoxide maritime transport imdg icaoiata class 4.
In general, hard bases give elimination and soft bases give substitution, but the gegenion has a. A sodium ethoxide solution freshly prepared from 2. Identification of the substancemixture and of the companyundertaking. The worldwide increase in biodiesel production has created a major market for sodium methoxide, as a catalyst in the transesterification of vegetable oils. The sodium ethoxide which is mixed in the solution ethanol will be colorless. Process simulation and technoeconomic analysis of the. Material safety data sheet section 1 1bromopentane 1 chemical product and company identification msds name.
Safety data sheet northwest missouri state university. Sodium ethoxide is an organic monosodium salt that has ethoxide as the counterion. Canadian ingredient disclosure list section 16 additional information msds creation date. Sodium methoxide is prepared by treating methanol with sodium. Find product specific information including properties, cas, msds, protocols and references. Sodium ethoxide msds material safety data sheet or sds, coa and coq, dossiers, brochures and other available documents. One reagent lane fair lawn, nj 07410 for information in north america. Application sodium ethoxide may be used as a base for the palladium catalyzed crosscoupling of aryl halides and alkenylboranes to. Ac168590000, ac168590010, ac168590050, ac168592500, ac168595000 synonyms. Skin contact wash off immediately with plenty of water for at least 15 minutes. For methanol, it is easier to get close, since the initial methanol can be obtained nearly anhydrous, so there is only 1 molar equivalent of water in the solution, whereas ethanol containing 5% water has a large amount more water than that. Intermediate for phenylbutazone, piroxicam,and so on. Sodium ethoxide 20% solution in ethanol for synthesis find msds or sds, a coa, data sheets and more information. Identification product name sodium ethoxide, 21% ww in.
Sodium ethoxide, 21% in ethanol safety data sheet aks741. Sodium ethoxide, 21% in ethanol revision date 19jan2018 attendance. Eye contact rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. This work evaluates different methods for the manufacture of sodium methoxide, diluted in methanol. Your new online msds binder is a place for you to store the material safety data sheets you need to deploy. Aks741 sodium ethoxide, 21% in ethanol sodium ethoxide, 21% in ethanol safety data sheet aks741 date of issue. Identification of the substancemixture and of the companyundertaking 1. Concerning your issue about the solubility of sodium methoxide with hexane.